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http://pesn.com/2005/04/14/6900082_Acetone_and_Alcohol/
You are here:
PureEnergySystems.com > News > April 14, 2005

Alcohol Apparently Inhibits Action of Acetone in Fuel

While inert in the fuel tank, under high temperature and pressure in the combustion chamber, acetone and alcohol are likely to react to form a ketone.

by Sterling D. Allan
Pure Energy Systems News

PROVO, UTAH, USA

As numerous people have been trying out acetone in small proportions in their fuel (e.g. 2 oz per 10 gallons), most of them are reporting increased mileage, more power, better idle, cleaner emissions.  Some have noted that acetone's performance seems to dwindle when added to fuel that has alcohol added.

Chat with a Professor

Wondering about the possible chemical interaction between these two molecules, acetone and alcohol, I phoned the local university, Brigham Young University, and asked for the chemistry department.  They connected me with Dr. Paul Savage, who seemed intrigued when I told him about the acetone phenomenon in fuel.  The theory that acetone is decreasing the fuel's surface tension, thereby increasing the amount of fuel that is fully vaporized, and thus able to combust seemed plausible to him.

He was not surprised at all when I informed him about a recent report of the smell of acetone emitting from a semi truck's fuel tank to which the acetone had been added.  "Acetone has a very high evaporation rate, much higher than fuel."  His secretary later gave me the name of three companies in Salt Lake that would be equipped to run a test to determine the exact rate of evaporation when mixed with fuel.  This is obviously a significant factor and will be important in determining the gradual loss of acetone from the tank over time if not used right away.

He was also not surprised at the observation that acetone does not seem to work as well when used in fuel that has alcohol in it.

"In the fuel, it is neutral.  It will not react before the combustion chamber.  But under conditions of pressure and heat, it can react."

He said that there are several possible pathways, but that the most likely reaction is:

acetone + alcohol ---> hemiacetal (aka himiketal)

which will also go to ---> acetal (aka ketal)

"This will obviously have an effect on how the acetone and alcohol behave," he said.  "The ketals will burn, but I don't know what they will do to the viscosity of the fuel, compared to acetone."  He recommended contacting a professor that specializes in fuel chemistry to probe the full ramifications.

He also observed that the oxygen on the acetone molecule is also likely to increase the oxygenation of the fuel, increasing its octane rating.

# # #

Related Stories

  • Lubricity of Acetone in Fuel; Ester's Solution - Acetone's positive results in mileage, idle, emissions, power, come in part from its engine cleaning effect, removing the carbon build-up. Does acetone degrade lubricity, creating long-term wear issues? Data from years of acetone use do not show unusual wear. Esters purported to afford added protection.

See also

 

Page composed by Sterling D. Allan Apr. 14, 2005
Last updated February 06, 2008

 

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